Competitive or sequential reaction of an electrophilic terminal phosphinidene metal(0) complex with allyl halides? [2+1]-cycloaddition vs. C–X bond insertion-Reference-Cited by-同舟云学术

Competitive or sequential reaction of an electrophilic terminal phosphinidene metal(0) complex with allyl halides? [2+1]-cycloaddition vs. C–X bond insertion

Published:2019 Issue:67 Volume:55 Page:9987-9990
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Khan Arif Ali¹²³⁴^ORCID,Junker Philip⁵⁶⁷⁸,Schnakenburg Gregor⁵⁶⁷⁸,Espinosa Ferao Arturo⁹¹⁰¹¹¹²¹³^ORCID,Streubel Rainer⁵⁶⁷⁸^ORCID

Affiliation:

1. University School of Basic and Applied Sciences

2. Guru Gobind Singh Indraprastha University

3. Dwarka, Sec.16-C

4. India

5. Institut für Anorganische Chemie

6. der Rheinischen Friedrich-Wilhelms-Universität Bonn

7. 53121 Bonn

8. Germany

9. Departamento de Química Orgánica

10. Facultad de Química

11. Campus de Espinardo

12. Universidad de Murcia

13. 30100 Murcia

Abstract

Transient terminal phosphinidene complex [(CO)₅WPCH(SiMe₃)₂] reacted with allyl halides (X = F, Cl, Br) to give different products. DFT calculations revealed a novel rearrangement with C → P X atom transfer of transient phosphirane complexes.

Funder

Universidad de Murcia

Deutsche Forschungsgemeinschaft

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC05328J

Reference39 articles.

1. Die Entwicklung einer carbenartigen Chemie von Phosphiniden-Übergangsmetallkomplexen

2. Electrophilic Terminal-Phosphinidene Complexes: Versatile Phosphorus Analogues of Singlet Carbenes

3. Carbene-Like Chemistry of Phosphinidene Complexes − Reactions, Applications, and Mechanistic Insights

4. A Singlet Phosphinidene Stable at Room Temperature

5. Developing the chemistry of monovalent phosphorus

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