Dehydrogenation reaction of triethylamine by an electrophilic terminal phosphinidene complex-Reference-Cited by-同舟云学术

Dehydrogenation reaction of triethylamine by an electrophilic terminal phosphinidene complex

Published:2023 Issue:11 Volume:52 Page:3275-3278
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Khan Arif Ali¹,Kalisch Tim²,Espinosa Ferao Arturo³^ORCID,Streubel Rainer²^ORCID

Affiliation:

1. University School of Basic & Applied Sciences, G.G.S. Indraprastha University, Dwarka, Sector-16C, New Delhi – 110078, India

2. Institut für Anorganische Chemie, der Rheinischen Friedrich-Wilhelms-Universität Bonn, Gerhard-Domagk-Str. 1, 53121 Bonn, Germany

3. Departamento de Química Orgánica, Facultad de Química Universidad de Murcia, Campus de Espinardo, 30100 Murcia, Spain

Abstract

A highly reactive, transiently formed terminal phosphinidene complex reacts with triethylamine to form a primary phosphane complex, eventually. The dehydrogenation is explained by a detailed, DFT-based mechanistic proposal.

Funder

Deutsche Forschungsgemeinschaft

Universidad de Murcia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00300K

Reference32 articles.

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