Pulse sequence and sample formulation optimization for dipolar order mediated 1H→13C cross-polarization-Reference-Cited by-同舟云学术

Pulse sequence and sample formulation optimization for dipolar order mediated 1H→13C cross-polarization

Published:2021 Issue:15 Volume:23 Page:9457-9465
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Elliott Stuart J.¹²³^ORCID,Cala Olivier¹²³,Stern Quentin¹²³,Cousin Samuel F.¹²³⁴⁵,Eshchenko Dmitry⁶⁷⁸,Melzi Roberto⁹¹⁰¹¹,Kempf James G.¹²¹³¹⁴,Jannin Sami¹²³

Affiliation:

1. Centre de Résonance Magnétique Nucléaire à Très Hauts Champs - FRE 2034 Université de Lyon/CNRS/Université Claude Bernard Lyon 1/ENS de Lyon

2. 69100 Villeurbanne

3. France

4. Institut de Chimie Radicalaire - UMR 7273

5. Saint-Jérôme Campus

6. Bruker Switzerland

7. 8117 Fällanden

8. Switzerland

9. Bruker Italia Srl

10. 20158 Milan

11. Italy

12. Bruker Biospin

13. Massachusetts

14. USA

Abstract

Optimization of a dipolar cross-polarization (dCP) sequence increases the efficiency of ¹H polarization transfers to ¹³C spins in a diverse range of molecular candidates with ¹³C polarizations surpassing 30%.

Funder

H2020 European Research Council

Horizon 2020

H2020 Marie Skłodowska-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP00429H

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1. Increase in signal-to-noise ratio of > 10,000 times in liquid-state NMR