Identifying different electronic transport mechanisms in nanoporous inorganic electrides – a combined study using Hall measurements and electron paramagnetic resonance spectroscopy

Author:

Dinter Julius K.1,Lange Jurek12,Hofmann Detlev M.12,Plaza Fernández J. Fabián3,Post Angel3,Chatterjee Sangam12ORCID,Elm Matthias T.124ORCID,Klar Peter J.12ORCID

Affiliation:

1. Center for Materials Research, Justus-Liebig University, Heinrich-Buff-Ring 16, D-35392, Giessen, Germany

2. Institute of Experimental Physics I, Justus-Liebig University, Heinrich-Buff-Ring 16, D-35392, Giessen, Germany

3. Advanced Thermal Devices, Calle Villaconejos, 4, E-28925 – Alcorcón, Spain

4. Institute of Physical Chemistry, Justus-Liebig University, Heinrich-Buff-Ring 17, D-35392, Giessen, Germany

Abstract

Temperature-dependent Hall measurements and electron paramagnetic resonance spectroscopy reveal that three different transport mechanisms contribute to the electronic properties of the inorganic electride [Ca24Al28O64]4+(4e).

Funder

European Commission

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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