Selective hydrogen production from formic acid decomposition over Mo carbides supported on carbon materials

Author:

Carrales-Alvarado D. H.1234,Dongil A. B.1234,Fernández-Morales J. M.5674ORCID,Fernández-García M.12348ORCID,Guerrero-Ruiz A.56748ORCID,Rodríguez-Ramos I.12348ORCID

Affiliation:

1. Instituto de Catálisis y Petroleoquímica

2. CSIC

3. 28049 Madrid

4. Spain

5. Dpto. Química Inorgánica y Técnica

6. Facultad de Ciencias UNED

7. 28040 Madrid

8. UA UNED-ICP (CSIC)

Abstract

The support influenced the carbide phase obtained so that a higher ratio of defective carbon favoured the formation of β-Mo2C phase vs. MoOxCy. Redox transformations during the reaction might be responsible of the transformation of β-Mo2C into MoOxCy.

Funder

European Regional Development Fund

Agencia Estatal de Investigación

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference43 articles.

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3. Hydrogen energy future with formic acid: a renewable chemical hydrogen storage system

4. Non-precious molybdenum-based catalyst derived from biomass: CO-free hydrogen production from formic acid at low temperature

5. Decomposition of formic acid for hydrogen production over metal doped nanosheet-like MoC 1−x catalysts

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