BF3·OEt2 catalyzed chemoselective CC bond cleavage of α,β-enones: an unexpected synthesis of 3-alkylated oxindoles and spiro-indolooxiranes-Reference-Cited by-同舟云学术

BF3·OEt2 catalyzed chemoselective CC bond cleavage of α,β-enones: an unexpected synthesis of 3-alkylated oxindoles and spiro-indolooxiranes

Published:2022 Issue:3 Volume:20 Page:558-564
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Muthusamy Sengodagounder¹^ORCID,Prabu Ammasi¹

Affiliation:

1. School of Chemistry, Bharathidasan University, Tiruchirappalli-620 024, India

Abstract

A BF3·OEt2 catalyzed highly chemoselective formal CC double bond cleavage reaction of α,β-enones with diazoamides for the synthesis of 3-alkylated oxindoles is developed.

Funder

University Grants Commission

Council of Scientific and Industrial Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/OB/D1OB02002A

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5. Radical C–C Bond Cleavage/Addition Cascade of Benzyl Cycloketone Oxime Ethers Enabled by Photogenerated Cyclic Iminyl Radicals

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