Acidity of the methyne group of poly(4-vinylpyridine) leads to side-chain protonation in pyridine-Reference-Cited by-同舟云学术

Acidity of the methyne group of poly(4-vinylpyridine) leads to side-chain protonation in pyridine

Published:2015 Issue:8 Volume:39 Page:5920-5922
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Vaganova Evgenia¹²³⁴,Rozenberg Mark¹²³⁴,Dubnikova Faina¹²³⁴,Danovich David⁵²⁶⁴,Yitzchaik Shlomo¹²³⁴

Affiliation:

1. Institute of Chemistry

2. The Hebrew University of Jerusalem

3. Jerusalem

4. Israel

5. Lise Meitner Minerva Center for Computational Quantum Chemistry and Institute of Chemistry

6. Jerusalem 91904

Abstract

Radiation sensitivity of poly(4-vinylpyridine)/pyridine likely involves side-chain N-protonation. IR spectroscopy shows that the proton donor is the methyne group CH.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/NJ/C5NJ01246E

Reference19 articles.

1. Synthesis of Poly(4-vinylpyridine) Thin Films by Initiated Chemical Vapor Deposition (iCVD) for Selective Nanotrench-Based Sensing of Nitroaromatics

2. Tailoring 1D ZnO Nanostructure Using Engineered Catalyst Enabled by Poly(4-vinylpyridine)

3. A general method to determine ionization constants of responsive polymer thin films

4. White Light and Heat Sensitivity in a Pyridine-Based Polymer Blend

5. Photoactive Proton Conductor: Poly(4-vinyl pyridine) Gel

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