Synthesis of silyl indenes by ruthenium-catalyzed aldehyde- and acylsilane-enabled C–H alkylation/cyclization-Reference-Cited by-同舟云学术

Synthesis of silyl indenes by ruthenium-catalyzed aldehyde- and acylsilane-enabled C–H alkylation/cyclization

Published:2024 Issue:3 Volume:22 Page:466-471
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Zhang Tao¹²,Zhang Cheng²,Lu Xiunan²,Peng Chengxing²,Zhang Yawei²,Zhu Xiong¹,Zhong Guofu²³^ORCID,Zhang Jian²^ORCID

Affiliation:

1. School of Engineering, China Pharmaceutical University, No. 24, Tongjiaxiang, Nanjing 210009, Jiangsu, China

2. College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, Hangzhou Normal University, Hangzhou, 311121 Zhejiang, China

3. Department of Chemistry, Eastern Institute for Advanced Study, Ningbo 315200, Zhejiang, China

Abstract

A ruthenium-catalyzed C–H alkylation/cyclization sequence is presented to prepare silyl indenes, which is triggered by acyl silane-directed C–H activation, and an aldehyde controls the following enol cyclization/condensation.

Funder

Natural Science Foundation of Zhejiang Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/OB/D3OB01699D

Reference93 articles.

1. Optimization of the Indenone Ring of Indenoisoquinoline Topoisomerase I Inhibitors

2. Effect of the Nature of Metallocene Complexes of Group IV Metals on Their Performance in Catalytic Ethylene and Propylene Polymerization

3. Synthesis and Characterization of 5,10-Bis(2-thienyl)indeno[2,1-a]indene Derivatives: The First Examples of Conducting Polymers Containing a Rigid Bis(thienyl)butadiene Core

4. The Synthesis of Indone and Some Related Compounds1

5. Indenone chemistry—II

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Synthesis Studies of Indene Derivatives;Journal of Organic Chemistry Research;2024