Visible-light induced oxidant-free oxidative cross-coupling for constructing allylic sulfones from olefins and sulfinic acids

Author:

Zhang Guoting1234,Zhang Lingling1234,Yi Hong1234,Luo Yi1234,Qi Xiaotian5674,Tung Chen-Ho8910114,Wu Li-Zhu8910114,Lei Aiwen123412

Affiliation:

1. College of Chemistry and Molecular Sciences, the Institute for Advanced Studies (IAS)

2. Wuhan University

3. Wuhan

4. P. R. China

5. School of Chemistry and Chemical Engineering

6. Chongqing University

7. Chongqing 400030

8. Key Laboratory of Photochemical Conversion and Optoelectronic Materials

9. Technical Institute of Physics and Chemistry & University of Chinese Academy of Sciences

10. Chinese Academy of Sciences

11. Beijing 100190

12. Lanzhou Institute of Chemical Physics

Abstract

An oxidant-free dehydrogenative sulfonylation of α-methyl-styrene derivatives was developed for the construction of allylic sulfones by using eosin Y as a photosensitizer in conjunction with a cobaloxime catalyst.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference45 articles.

1. Chiral Sulfur Ligands for Asymmetric Catalysis

2. Organic Semiconducting Oligomers for Use in Thin Film Transistors

3. Discovery of 5-Arylsulfonamido-3- (pyrrolidin-2-ylmethyl)-1H-indole Derivatives as Potent, Selective 5-HT6 Receptor Agonists and Antagonists

4. I. P. Beletskaya and V. P.Ananikov, Catalyzed Carbon-Heteroatom Bond Formation, Wiley-VCH Verlag GmbH & Co. KGaA, 2010, ch. 3pp. 69–118

5. P. Bichler and J.Love, in C-X Bond Formation, ed. A. Vigalok, Springer, Berlin Heidelberg, 2010, ch. 3, vol. 31, pp. 39–64

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