Quantum coherence effects in natural light-induced processes: cis–trans photoisomerization of model retinal under incoherent excitation

Author:

Tscherbul Timur V.12345,Brumer Paul12345

Affiliation:

1. Chemical Physics Theory Group

2. Department of Chemistry

3. and Center for Quantum Information and Quantum Control

4. University of Toronto

5. Toronto

Abstract

CisTrans isomerization of retinal induced by incoherent solar light. Shown are ground and excited-state diabatic potentials; the horizontal lines represent bright eigenstates (red), intermediate eigenstates (blue), and product eigenstates (green). The inset: the photoreaction efficiency vs. time with (red) and without (blue) Fano coherences.

Funder

Air Force Office of Scientific Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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