Heteroaryl bismuthines: a novel synthetic concept and metal⋯π heteroarene interactions-Reference-Cited by-同舟云学术

Heteroaryl bismuthines: a novel synthetic concept and metal⋯π heteroarene interactions

Published:2017 Issue:25 Volume:46 Page:8269-8278
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Preda A. M.¹²³⁴⁵,Schneider W. B.¹²³⁴⁵,Rainer M.¹²³⁴⁵,Rüffer T.¹²³⁴⁵^ORCID,Schaarschmidt D.¹²³⁴⁵,Lang H.¹²³⁴⁵,Mehring M.¹²³⁴⁵^ORCID

Affiliation:

1. Technische Universität Chemnitz

2. Fakultät für Naturwissenschaften

3. Institut für Chemie

4. 09107 Chemnitz

5. Germany

Abstract

We report a new synthetic route for heteroaryl bismuth compounds, formed from silanol-alcoholate/amide exchange resulting in the formation of bismuth carbon bonds. Their structures in the solid state reveal London dispersion type bismuth⋯π interactions that determine the supramolecular assemblies.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01437F

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