Stabilizing Effect of Pre-equilibria: A Trifluoromethyl Complex as a CF<sub>2</sub> Reservoir in Catalytic Olefin Difluorocarbenation-Reference-Cited by-同舟云学术

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Stabilizing Effect of Pre-equilibria: A Trifluoromethyl Complex as a CF₂ Reservoir in Catalytic Olefin Difluorocarbenation

Published:2022-03-09 Issue:6 Volume:12 Page:3719-3730
ISSN:2155-5435
Container-title:ACS Catalysis
language:en
Short-container-title:ACS Catal.

Author:

Louis-Goff Thomas¹,Trinh Huu Vinh¹,Chen Eileen¹,Rheingold Arnold L.²^ORCID,Ehm Christian³^ORCID,Hyvl Jakub¹^ORCID

Affiliation:

1. Department of Chemistry, University of Hawai‘i at Ma̅noa, 2545 McCarthy Mall, Honolulu, Hawaii 96822, United States

2. Department of Chemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, California 92093, United States

3. Dipartimento di Scienze Chimiche, Università di Napoli Federico II, Via Cintia, 80126 Napoli, Italy

Funder

Division of Chemistry

University of Hawai'i at Manoa

Publisher

American Chemical Society (ACS)

Subject

Catalysis,General Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acscatal.1c05959

Reference92 articles.

1. Applications of Fluorine in Medicinal Chemistry

2. Catalysis for fluorination and trifluoromethylation

3. Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

4. The Unique Role of Fluorine in the Design of Active Ingredients for Modern Crop Protection

5. Structure, Synthesis, and Chemical Reactions of Fluorinated Cyclopropanes and Cyclopropenes

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1. Reductive Cyclopropanation through Bismuth Photocatalysis;Journal of the American Chemical Society;2024-08-05

2. Synthesis of Difluorocyclopropanes via Visible‐Light‐Mediated [1+2] Cycloaddition of Diazo Esters with gem‐Difluoroalkenes and Evaluation of their Antifungal Activity;Advanced Synthesis & Catalysis;2024-03-07

3. Bi-Catalyzed Trifluoromethylation of C(sp²)–H Bonds under Light;Journal of the American Chemical Society;2023-11-14

4. Synthesis of Aryl‐Manganese(III) Fluoride Complexes via α‐Fluorine Elimination from CF₃ and Difluorocarbene Generation;European Journal of Inorganic Chemistry;2023-09-13

5. Synthesis of Chiral Hypervalent Trifluoromethyl Organobismuth Complexes and Enantioselective Olefin Difluorocarbenation Screenings;ChemPlusChem;2023-02

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