Understanding the mechanism of transition metal-free anti addition to alkynes: the selenoboration case-Reference-Cited by-同舟云学术

Understanding the mechanism of transition metal-free anti addition to alkynes: the selenoboration case

Published:2018 Issue:14 Volume:8 Page:3617-3628
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

García-López Diego¹²³⁴,Civit Marc G.¹²³⁴,Vogels Christopher M.⁵⁶⁷⁸,Ricart Josep M.¹²³⁴^ORCID,Westcott Stephen A.⁵⁶⁷⁸^ORCID,Fernández Elena¹²³⁴^ORCID,Carbó Jorge J.¹²³⁴^ORCID

Affiliation:

1. Departament de Química Física i Inorgànica

2. Universitat Rovira i Virgili

3. Tarragona

4. Spain

5. Department of Chemistry and Biochemistry

6. Mount Allison University

7. Sackville

8. Canada

Abstract

A novel mechanism was proposed for the stereoselective anti-addition of selenoboranes to alkynes using catalytic amounts of PCy₃.

Funder

Ministerio de Economía y Competitividad

Natural Sciences and Engineering Research Council of Canada

Generalitat de Catalunya

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CY/C7CY02295F

Reference51 articles.

1. Boron-selective reactions as powerful tools for modular synthesis of diverse complex molecules

2. Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

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4. Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments

5. Copper-Catalyzed trans-Hydroboration of Terminal Aryl Alkynes: Stereodivergent Synthesis of Alkenylboron Compounds

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