Monomeric Cp3tAl(i): synthesis, reactivity, and the concept of valence isomerism

Author:

Hofmann Alexander12345,Tröster Tobias12345,Kupfer Thomas12345,Braunschweig Holger12345ORCID

Affiliation:

1. Institut für Anorganische Chemie

2. Julius-Maximilians-Universität Würzburg

3. 97074 Würzburg

4. Germany

5. Institute for Sustainable Chemistry & Catalysis with Boron

Abstract

With Cp3tAl, a monomeric Al(i) species was isolated, which reacted faster, more selectively, and under milder conditions than well-known tetrameric (Cp*Al)4.

Funder

Julius-Maximilians-Universität Würzburg

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference47 articles.

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2. The Renaissance of Aluminum Chemistry

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4. Metalloid Aluminum and Gallium Clusters: Element Modifications on the Molecular Scale?

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