Mechanochemical Synthesis of Non‐Solvated Dialkylalumanyl Anion and XPS Characterization of Al(I) and Al(II) Species**-Reference-Cited by-同舟云学术

Mechanochemical Synthesis of Non‐Solvated Dialkylalumanyl Anion and XPS Characterization of Al(I) and Al(II) Species**

Published:2023-12-11 Issue:7 Volume:30 Page:
ISSN:0947-6539
Container-title:Chemistry – A European Journal
language:en
Short-container-title:Chemistry A European J

Author:

Kurumada Satoshi¹,Yamanashi Ryotaro¹,Sugita Kengo¹,Kubota Koji²³,Ito Hajime²³^ORCID,Ikemoto Satoru⁴,Chen Chaoqi⁴,Moriyama Takumi⁴,Muratsugu Satoshi⁴⁵^ORCID,Tada Mizuki⁴⁵⁶^ORCID,Koitaya Takanori⁷^ORCID,Ozaki Taisuke⁸,Yamashita Makoto¹⁵^ORCID

Affiliation:

1. Department of Molecular and Macromolecular Chemistry Graduate School of Engineering Nagoya University Furo-cho, Chikusa-ku 464-8603 Nagoya Aichi Japan

2. Division of Applied Chemistry Graduate School of Engineering Hokkaido University 060-8628 Sapporo Hokkaido Japan

3. Institute for Chemical Reaction Design and Discovery (WPI-ICReDD) Hokkaido University 060-8628 Sapporo Hokkaido Japan

4. Department of Chemistry Graduate School of Science Nagoya University Furo-cho, Chikusa-ku 464-8603 Nagoya Aichi Japan

5. Integrated Research Consortium on Chemical Science (IRCCS) Nagoya University Furo-cho, Chikusa-ku 464-8602 Nagoya Aichi Japan

6. Research Center for Materials Science (RCMS) Nagoya University Furo-cho, Chikusa-ku 464-8602 Nagoya Aichi Japan

7. Department of Chemistry Graduate School of Science Kyoto University Kitashirakawa-Oiwake-cho, Sakyo-ku 606-8502 Kyoto Japan

8. The Institute for Solid State Physics The University of Tokyo 5-1-5 Kashiwanoha 277-8581 Kashiwa Chiba Japan

Abstract

AbstractA non‐solvated alkyl‐substituted Al(I) anion dimer was synthesized by a reduction of haloalumane precursor using a mechanochemical method. The crystallographic and theoretical analysis revealed its structure and electronic properties. Experimental XPS analysis of the Al(I) anions with reference compounds revealed the lower Al 2p binding energy corresponds to the lower oxidation state of Al species. It should be emphasized that the experimentally obtained XPS binding energies were reproduced by delta SCF calculations and were linearly correlated with NPA charges and 2p orbital energies.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Japan Science and Technology Corporation

Japan Society for the Promotion of Science London

Publisher

Wiley

Subject

General Chemistry,Catalysis,Organic Chemistry

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