The synthesis of sterically hindered amines by a direct reductive amination of ketones-Reference-Cited by-同舟云学术

The synthesis of sterically hindered amines by a direct reductive amination of ketones

Published:2016 Issue:7 Volume:52 Page:1397-1400
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yagafarov Niyaz Z.¹²³,Kolesnikov Pavel N.¹²³,Usanov Dmitry L.¹²³,Novikov Valentin V.¹²³,Nelyubina Yulia V.¹²³,Chusov Denis¹²³

Affiliation:

1. A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

2. Moscow

3. Russian Federation

Abstract

An atom-economical methodology for the synthesis of sterically hindered tertiary amines was developed, which is based on a complementary Rh- and Ru-catalyzed direct reductive amination of ketones with primary and secondary amines using carbon monoxide as a deoxygenating agent.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C5CC08577B

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