Double-step CO2 sorption and guest-induced single-crystal-to-single-crystal transformation in a flexible porous framework-Reference-Cited by-同舟云学术

Double-step CO2 sorption and guest-induced single-crystal-to-single-crystal transformation in a flexible porous framework

Published:2015 Issue:22 Volume:44 Page:10141-10145
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wu Wei-Ping¹²³⁴⁵,Li Zhi-Sen¹²³⁴⁵,Liu Bo¹²³⁴⁵,Liu Ping¹²³⁴⁵,Xi Zheng-Ping¹²³⁴⁵,Wang Yao-Yu¹²³⁴⁵

Affiliation:

1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education

2. Shaanxi Key Laboratory of Physico-Inorganic Chemistry

3. College of Chemistry & Materials Science

4. Northwest University

5. Xi'an 710069

Abstract

A new 2D highly flexible and breathing porous coordination polymer has been synthesized, which exhibits selective and double-step hysteretic adsorption for CO₂, and shows a single-crystal-to-single-crystal transformation induced by CH₂Cl₂ at room temperature.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00460H

Reference53 articles.

1. Very Large Breathing Effect in the First Nanoporous Chromium(III)-Based Solids: MIL-53 or CrIII(OH)·{O2C−C6H4−CO2}·{HO2C−C6H4−CO2H}x·H2Oy

2. Porous Coordination-Polymer Crystals with Gated Channels Specific for Supercritical Gases

3. Discrimination of Small Gas Molecules through Adsorption: Reverse Selectivity for Hydrogen in a Flexible Metal−Organic Framework

4. How Hydration Drastically Improves Adsorption Selectivity for CO2 over CH4 in the Flexible Chromium Terephthalate MIL-53

5. Kinetic Gate-Opening Process in a Flexible Porous Coordination Polymer

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