First-principles microkinetic study of methane and hydrogen sulfide catalytic conversion to methanethiol/dimethyl sulfide on Mo6S8 clusters: activity/selectivity of different promoters

Author:

Arvidsson Adam A.1234ORCID,Taifan William5678,Hellman Anders1234ORCID,Baltrusaitis Jonas5678ORCID

Affiliation:

1. Department of Physics

2. Chalmers University of Technology

3. 412 96 Gothenburg

4. Sweden

5. Department of Chemical and Biomolecular Engineering

6. Lehigh University

7. Bethlehem

8. USA

Abstract

A large fraction of the global natural gas reserves is in the form of sour gas, i.e. contains hydrogen sulfide (H2S) and carbon dioxide (CO2), and needs to be sweetened before utilization.

Funder

Vetenskapsrådet

Basic Energy Sciences

Knut och Alice Wallenbergs Stiftelse

Röntgen-Ångström Cluster

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference70 articles.

1. V. Subramani , P.Sharma , L.Zhang and K.Liu , in Hydrogen and Syngas Production and Purification Technologies , John Wiley & Sons, Inc. , 2009 , pp. 14–126

2. Olefin Metathesis by Supported Metal Oxide Catalysts

3. OLEFIN METATHESIS: BIG-DEAL REACTION

4. Alumina Catalysts in Low-Temperature Claus Process

5. CH 4 conversion to value added products: Potential, limitations and extensions of a single step heterogeneous catalysis

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