Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis-Reference-Cited by-同舟云学术

Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis

Published:2023 Issue:12 Volume:13 Page:3709-3724
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Kirchhof Manuel¹,Gugeler Katrin²,Beurer Ann-Katrin³,Fischer Felix Richard⁴,Batman Derman¹,Bauch Soeren M.²,Kolin Sofia²,Nicholas Elliot¹,Schoch Roland⁵^ORCID,Vogler Charlotte⁶,Kousik Shravan R.⁷,Zens Anna¹^ORCID,Plietker Bernd⁴,Atanasova Petia⁷,Naumann Stefan⁶^ORCID,Bauer Matthias⁵^ORCID,Bruckner Johanna R.⁸^ORCID,Traa Yvonne³^ORCID,Kästner Johannes²^ORCID,Laschat Sabine¹^ORCID

Affiliation:

1. Institute of Organic Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany

2. Institute for Theoretical Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany

3. Institute of Technical Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany

4. Chair of Organic Chemistry I, Technical University of Dresden, 01069 Dresden, Germany

5. Department Chemistry and Center for Sustainable Systems Design (CSSD), University of Paderborn, 33098 Paderborn, Germany

6. Institute of Polymer Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany

7. Institute for Materials Science, University of Stuttgart, Heisenbergstr. 3, 70569 Stuttgart, Germany

8. Institute of Physical Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany

Abstract

Improved enantioselectivity in the 1,2-addition was observed for chiral Rh norbornadiene catalysts immobilized on ordered mesoporous silica with small pores. Confinement effects were rationalized by experimental and computational studies.

Funder

Deutsche Forschungsgemeinschaft

Ministerium für Wissenschaft, Forschung und Kunst Baden-Württemberg

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CY/D3CY00381G

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