An amide-based second coordination sphere promotes the dimer pathway of Mn-catalyzed CO2-to-CO reduction at low overpotential-Reference-Cited by-同舟云学术

An amide-based second coordination sphere promotes the dimer pathway of Mn-catalyzed CO2-to-CO reduction at low overpotential

Published:2021 Issue:13 Volume:12 Page:4779-4788
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Yang Yong¹²³⁴⁵,Ertem Mehmed Z.⁶⁷⁸⁹¹⁰,Duan Lele¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Shenzhen Grubbs Institute and Guangdong Provincial Key Laboratory of Energy Materials for Electric Power

3. Southern University of Science and Technology

4. Shenzhen

5. China

6. Chemistry Division

7. Energy & Photon Sciences

8. Brookhaven National Laboratory

9. Upton

10. USA

Abstract

The amide NH group decreases the overpotential of Mn-based CO₂ reduction catalysts by promoting the dimer and protonation-first pathways in the presence of H₂O and enhances the CO₂ electroreduction activity by facilitating C–OH bond cleavage.

Funder

National Natural Science Foundation of China

Office of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC05679K

Reference68 articles.

1. Electrocatalytic and homogeneous approaches to conversion of CO2to liquid fuels

2. Progress toward Commercial Application of Electrochemical Carbon Dioxide Reduction