Porosity induced rigidochromism in platinum(ii) terpyridyl luminophores immobilized at silica composites

Author:

Norton Amie E.1ORCID,Zanoni Kassio P. S.2ORCID,Dourges Marie-Anne3ORCID,Ravaro Leandro P.2ORCID,Abdolmaleki Mahmood K.1ORCID,de Camargo Andrea S. S.2ORCID,Toupance Thierry3ORCID,Connick William B.1,Chatterjee Sayandev4ORCID

Affiliation:

1. Department of Chemistry, University of Cincinnati, Cincinnati, OH 45220, USA

2. Laboratório de Espectroscopia de Materiais Funcionais (LEMAF), Instituto de Física de São Carlos, Universidade de São Paulo, 13566-590, São Carlos, SP, Brazil

3. Univ. Bordeaux, Institute of Molecular Sciences, UMR 5255 CNRS, 351 Cours de la Libération, F-33405 Talence Cédex, France

4. ESSENCE Diagnostics LLC, Livingston, NJ 07039, USA

Abstract

This work explores a methodology where immobilization of square planar platinum(ii) terpyridyl luminophores onto meso/microporous silica alters the Pt(ii) electronic structure, inducing a rigidochromic behavior that is dictated by the silica porosity.

Funder

National Science Foundation

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Fundação de Amparo à Pesquisa do Estado de São Paulo

U.S. Environmental Protection Agency

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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