Optical sensing of aqueous nitrate anion by a platinum(ii) triimine salt based solid state material

Author:

Norton Amie E.1ORCID,Karimi Abdolmaleki Mahmood1ORCID,Andriot Logan1,Cashen Christina1,Krause Jeanette A.1,Connick William B.1,Chatterjee Sayandev2

Affiliation:

1. Department of Chemistry, University of Cincinnati, Cincinnati, OH, 45221, USA

2. TerraPower LLC, Bellevue, WA, 98008, USA

Abstract

Selective and quantitative measurement of aqueous nitrate (NO3) anion is achieved using solid [Pt(Cl-4-tpy)Cl]ClO4 salt (Cl-4-tpy = 4-chloro-2,2′:6′2′′-terpyridine), and as the salt supported on controlled porous glass.

Funder

Department of Energy and Climate Change

National Science Foundation

U.S. Environmental Protection Agency

Lawrence Berkeley National Laboratory

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference29 articles.

1. Highly Selective Colorimetric and Luminescence Response of a Square-Planar Platinum(II) Terpyridyl Complex to Aqueous TcO4–

2. Solid-state materials for anion sensing in aqueous solution: highly selective colorimetric and luminescence-based detection of perchlorate using a platinum(ii) salt

3. Identification of Inorganic Improvised Explosive Devices Using Sequential Injection Capillary Electrophoresis and Contactless Conductivity Detection

4. J. J.Brady , P. M. F.Iv , J. J.Perez , E. J.Judge and R. J.Levis , in Chemical, Biological, Radiological, Nuclear, and Explosives (CBRNE) Sensing XIII , SPIE , 2012 , vol. 8358, pp. 242–250

5. B.Yellampelle , M.Sluch , S.Asher and B.Lemoff , in Chemical, Biological, Radiological, Nuclear, and Explosives (CBRNE) Sensing XII , SPIE , 2011 , vol. 8018, pp. 353–359

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