Light and oxygen-enabled sodium trifluoromethanesulfinate-mediated selective oxidation of C

Light and oxygen-enabled sodium trifluoromethanesulfinate-mediated selective oxidation of C–H bonds

Published:2020 Issue:13 Volume:22 Page:4357-4363
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Zhu Xianjin¹²³⁴⁵,Liu Yong¹²³⁴⁵,Liu Can¹²³⁴⁵,Yang Haijun¹²³⁴⁵,Fu Hua¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology (Ministry of Education)

2. Department of Chemistry

3. Tsinghua University

4. Beijing 100084

5. China

Abstract

A light and oxygen-enabled sodium trifluoromethanesulfinate-mediated selective oxidation of C–H bonds has been developed. High-value-added aromatic ketones and carboxylic acids were easily prepared in high-to-excellent yields using readily available starting materials.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/GC/D0GC00383B

Reference59 articles.

1. Merging Photoredox Catalysis with Organocatalysis: The Direct Asymmetric Alkylation of Aldehydes

2. Alcohols as alkylating agents in heteroarene C–H functionalization

3. Aryl amination using ligand-free Ni(II) salts and photoredox catalysis