On the competition between six-membered and five-membered NHC towards alane centered ring expansion-Reference-Cited by-同舟云学术

On the competition between six-membered and five-membered NHC towards alane centered ring expansion

Published:2023 Issue:55 Volume:59 Page:8540-8543
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Balayan Kajal¹²^ORCID,Sharma Himanshu²³^ORCID,Vanka Kumar²³^ORCID,Ravindranathan Sapna²⁴,Gonnade Rajesh G.²³^ORCID,Sen Sakya S.¹²^ORCID

Affiliation:

1. Inorganic Chemistry and Catalysis Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pashan, Pune 411008, India

2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

3. Physical and Material Chemistry Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pashan, Pune 411008, India

4. Central NMR Facility, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pashan, Pune 411008, India

Abstract

The reactions of 6-SIDipp·AlH3 (1) with 5-IDipp or 5-IDipp·AlH3 with 6-SIDipp resulted in the ring expansion of six-membered NHC, while the five-membered NHC remained intact.

Funder

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC02063K

Reference28 articles.

1. Beryllium-Induced CN Bond Activation and Ring Opening of an N-Heterocyclic Carbene

2. CN Bond Cleavage and Ring Expansion of N-Heterocyclic Carbenes using Hydrosilanes

3. Preparation of Stable Low-Oxidation-State Group 14 Element Amidohydrides and Hydride-Mediated Ring-Expansion Chemistry of N-Heterocyclic Carbenes

4. Systematic Investigation of the Ring-Expansion Reaction of N-Heterocyclic Carbenes with an Iminoborane Dihydride

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