Ambiphilicity of ring-expanded N-heterocyclic carbenes-Reference-Cited by-同舟云学术

Ambiphilicity of ring-expanded N-heterocyclic carbenes

Published:2024 Issue:10 Volume:15 Page:3707-3710
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Vermersch François¹^ORCID,Wang Victor T.¹^ORCID,Abdellaoui Mehdi¹^ORCID,Jazzar Rodolphe¹^ORCID,Bertrand Guy¹^ORCID

Affiliation:

1. UCSD-CNRS Joint Research Chemistry Laboratory (IRL 3555), Department of Chemistry and Biochemistry, University of California, La Jolla, San Diego, California 92093-0358, USA

Abstract

Contrasting with popular beliefs, experimental and theoretical data show that some N-heterocyclic carbenes (NHCs), especially the seven and eight membered rings NHCs, are very ambiphilic.

Funder

U.S. Department of Energy

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC04543A

Reference49 articles.

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5. Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

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