Hydroboration of carbonyls and imines by an iminophosphonamido tin(ii) precatalyst

Author:

Nakaya Kazuki1,Takahashi Shintaro1,Ishii Akihiko1ORCID,Boonpalit Kajjana2ORCID,Surawatanawong Panida2ORCID,Nakata Norio1ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Science and Engineering, Saitama University, 255 Shimo-okubo, Sakura-ku, Saitama 338-8570, Japan

2. Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahidol University, Bangkok 10400, Thailand

Abstract

Iminophosphonamido tin(ii) chloride 1 can act as a precatalyst for the hydroboration of aldehydes, ketones, and imines at −10 °C.

Funder

Japan Society for the Promotion of Science

Shorai Foundation for Science and Technology

Thailand Research Fund

Center of Excellence for Innovation in Chemistry

Japan Science and Technology Corporation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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