A biomimetic synthesis-enabled stereochemical assignment of rhodotomentones A and B, two unusual caryophyllene-derived meroterpenoids from Rhodomyrtus tomentosa-Reference-Cited by-同舟云学术

A biomimetic synthesis-enabled stereochemical assignment of rhodotomentones A and B, two unusual caryophyllene-derived meroterpenoids from Rhodomyrtus tomentosa

Published:2021 Issue:20 Volume:8 Page:5728-5735
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Deng Lu-Ming¹²,Hu Li-Jun¹²,Tang Wei¹²,Liu Jia-Xin¹²,Huang Xiao-Jun¹²,Li Yue-Yue²,Li Yao-Lan²,Ye Wen-Cai¹²^ORCID,Wang Ying¹²

Affiliation:

1. Center for Bioactive Natural Molecules and Innovative Drugs Research, College of Pharmacy, Jinan University, Guangzhou 510632, People's Republic of China

2. Guangdong Province Key Laboratory of Pharmacodynamic Constituents of TCM & New Drugs Research, Jinan University, Guangzhou 510632, People's Republic of China

Abstract

Rhodotomentones A and B (1 and 2), two unusual caryophyllene-derived meroterpenoids (CDMTs) featuring a rare 6/6/9/4/6/6 hexacyclic ring system, along with their biogenetically-related CDMTs 7 and 12–15, were isolated from Rhodomyrtus tomentosa.

Funder

National Natural Science Foundation of China

Guangdong Provincial Pearl River Talents Program

Natural Science Foundation of Guangdong Province

National Key Research and Development Program of China

Special Project for Research and Development in Key areas of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QO/D1QO00989C