Probing the dynamics of the photo-induced decarboxylation of neutral and ionic pyruvic acid-Reference-Cited by-同舟云学术

Probing the dynamics of the photo-induced decarboxylation of neutral and ionic pyruvic acid

Published:2022 Issue: Volume:238 Page:266-294
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Jarraya M.¹²,Bellili A.³,Barreau L.⁴^ORCID,Cubaynes D.⁴,Garcia G. A.⁵^ORCID,Poisson L.⁴^ORCID,Hochlaf M.¹^ORCID

Affiliation:

1. U. Gustave Eiffel, COSYS/LISIS, 5 Bd Descartes 77454, Champs-sur-Marne, France

2. Laboratoire de Spectroscopie Atomique, Moléculaire et Applications – LSAMA, Université de Tunis El Manar, Tunis, Tunisia

3. U. Houari Boumediene des Sciences et Technologies, LTMM, Algiers, Algeria

4. Université Paris-Saclay, CNRS, Institut des Sciences Moléculaires d’Orsay, Orsay, 91405, France

5. Synchrotron SOLEIL, L’Orme des Merisiers, Saint-Aubin, BP 48-91192, Gif-sur-Yvette Cedex, France

Abstract

Combined advanced ab initio treatments and experiments reveal that the pyruvic acid cation decomposes to mostly form HOCO, in contrast to the photodynamics of electronically excited pyruvic acid being dominated by decarboxylation.

Funder

European Cooperation in Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/FD/D2FD00023G

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