Accounting for molecular flexibility in photoionization: case of <i>tert</i>-butyl hydroperoxide-Reference-Cited by-同舟云学术

Accounting for molecular flexibility in photoionization: case of tert-butyl hydroperoxide

Published:2022 Issue:18 Volume:24 Page:10826-10837
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Bourgalais Jérémy¹^ORCID,Jiang Zhongming²^ORCID,Bloino Julien²^ORCID,Herbinet Olivier¹^ORCID,Carstensen Hans-Heinrich³⁴^ORCID,Garcia Gustavo A.⁵^ORCID,Arnoux Philippe¹,Tran Luc-Sy⁶,Vanhove Guillaume⁶^ORCID,Nahon Laurent⁵^ORCID,Battin-Leclerc Frédérique¹^ORCID,Hochlaf Majdi⁷^ORCID

Affiliation:

1. Université de Lorraine, CNRS, LRGP, F-54000 Nancy, France

2. SMART Laboratory, Scuola Normale Superiore, Pisa, Italy

3. Thermochemical Processes Group (GPT), Department of Chemical and Environmental Engineering, Engineering and Architecture School, University of Zaragoza, Spain

4. Fundacion Agencia Aragonesa para la Investigacion y el Desarrollo (ARAID), Zagaroza, Spain

5. Synchrotron SOLEIL, L’Orme des Merisiers, Saint-Aubin-BP 48, 91192 Gif-sur-Yvette Cedex, France

6. PC2A, Université de Lille, CNRS, Avenue Mendeleiev, 59650 Villeneuve-d'Ascq, France

7. Université Gustave Eiffel, COSYS/LISIS, 5 Bd Descartes 77454, Champs sur Marne, France

Abstract

We use synchrotron-based VUV single photon ionization and advanced theoretical simulations to unravelling the dissociative ionization of tert-butyl hydroperoxide where special treatment is undertaken because of the flexibility of this molecule.

Funder

Association Franck, Un Rayon de Soleil

Federación Española de Enfermedades Raras

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP00929C

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1. Labile Peroxides in Secondary Organic Aerosol

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