Pd/Cu-catalyzed dual C–H bond carbonylation towards the synthesis of fluorazones-Reference-Cited by-同舟云学术

Pd/Cu-catalyzed dual C–H bond carbonylation towards the synthesis of fluorazones

Published:2017 Issue:31 Volume:53 Page:4354-4357
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Liao Fan¹²³⁴,Shi Renyi⁵⁶⁷⁸⁴,Sha Yuchen⁵⁶⁷⁸⁴,Xia Jianhui¹²³⁴,Liao Weilin¹²³⁴,Lei Aiwen¹²³⁴⁵^ORCID

Affiliation:

1. National Research Center for Carbohydrate Synthesis

2. Jiangxi Normal University

3. Nanchang 330022

4. P. R. China

5. College of Chemistry and Molecular Sciences

6. Institute for Advanced Studies (IAS)

7. Wuhan University

8. Wuhan 430072

Abstract

Pd catalyzed oxidative dual C–H bond activation/carbonylation still remains a great challenge due to the generation of by-products via C–C bond formation. Herein, we developed a straightforward Pd/Cu-catalyzed oxidative dual C–H bond carbonylation process to access biologically and pharmaceutically important fluorazones from easily available N-aryl pyrroles and CO utilizing O₂ as the terminal oxidant.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC01707C

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