Palladium-catalyzed direct carbonylation of thiophenes and furans under CO/CO2-binary conditions leading to carboxylic acids

Author:

Yamamoto Yuki1ORCID,Kurata Daichi2,Ogawa Akiya3ORCID

Affiliation:

1. Graduate Faculty of Interdisciplinary Research, University of Yamanashi, 4-4-37 Takeda, Kofu, Yamanashi 400-8510, Japan

2. Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan

3. Organization for Research Promotion, Osaka Metropolitan University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan

Abstract

In this study, novel catalytic carbonylation of thiophenes and furans was successfully achieved by using a catalytic amount of Pd(OAc)2 (min. 1 mol%) under CO/CO2-binary conditions.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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