Tripyrrin-armed isosmaragdyrins: synthesis, heterodinuclear coordination, and protonation-triggered helical inversion-Reference-Cited by-同舟云学术

Tripyrrin-armed isosmaragdyrins: synthesis, heterodinuclear coordination, and protonation-triggered helical inversion

Published:2020 Issue:10 Volume:11 Page:2790-2795
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Li Chengjie¹²³⁴⁵^ORCID,Zhang Kai¹²³⁴⁵,Ishida Masatoshi⁶⁷⁸⁹¹⁰^ORCID,Li Qizhao¹²³⁴⁵,Shimomura Keito⁶⁷⁸⁹¹⁰,Baryshnikov Glib¹¹¹²¹³¹⁴^ORCID,Li Xin¹¹¹²¹³¹⁴,Savage Mathew¹⁵¹⁶¹⁷¹⁸^ORCID,Wu Xin-Yan¹²³⁴⁵^ORCID,Yang Sihai¹⁵¹⁶¹⁷¹⁸^ORCID,Furuta Hiroyuki⁶⁷⁸⁹¹⁰^ORCID,Xie Yongshu¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory for Advanced Materials

2. Joint International Research Laboratory of Precision Chemistry and Molecular Engineering

3. Feringa Nobel Prize Scientist Joint Research Center

4. Shanghai Key Laboratory of Functional Materials Chemistry

5. School of Chemistry and Molecular Engineering

6. Department of Chemistry and Biochemistry

7. Graduate School of Engineering

8. Center for Molecular Systems

9. Kyushu University

10. Fukuoka 819-0395

11. School of Biotechnology

12. KTH Royal Institute of Technology

13. SE-10691 Stockholm

14. Sweden

15. School of Chemistry

16. University of Manchester

17. Manchester M13 9PL

18. UK

Abstract

A tripyrrin-armed isosmaragdyrin containing a β,β-linked bipyrrole moiety has been synthesized from a linear octapyrrole, and the succeeding metallation afforded an enantiomer pair of mononuclear Ni^II- and heterodinuclear Ni^II/Cu^II-complexes that exhibit P- and M-helices.

Funder

Japan Society for the Promotion of Science

National Natural Science Foundation of China

Tokuyama Science Foundation

Science and Technology Commission of Shanghai Municipality

Fundamental Research Funds for the Central Universities

Program of Introducing Talents of Discipline to Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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