Mono- and bis-Pd(ii) complexes of N-confused dithiahexaphyrin(1.1.1.1.1.0) with the absorption and aromaticity modulated by Pd(ii) coordination, macrocycle contraction and ancillary ligands

Author:

Sun Meng1,Xie Yongshu12ORCID,Baryshnikov Glib3ORCID,Li Chengjie1ORCID,Sha Feng1ORCID,Wu Xinyan1ORCID,Ågren Hans4,Li Shijun2ORCID,Li Qizhao1ORCID

Affiliation:

1. Key Laboratory for Advanced Materials, Frontiers Science Center for Materiobiology and Dynamic Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China

2. College of Material, Chemistry and Chemical Engineering, Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou, 311121, China

3. Department of Science and Technology, Laboratory of Organic Electronics, Linköping University, SE-601 74 Norrköping, Sweden

4. Department of Physics and Astronomy, Uppsala University, SE-751 20 Uppsala, Sweden

Abstract

From a single N-confused dithiahexaphyrin ligand, five mono- and bis-Pd(ii) complexes have been synthesized, and the absorption and aromaticity can be modulated by Pd(ii) coordination, macrocycle contraction and ancillary ligands.

Funder

Shanghai Rising-Star Program

Fundamental Research Funds for the Central Universities

Natural Science Foundation of Shanghai Municipality

National Natural Science Foundation of China

Vetenskapsrådet

Publisher

Royal Society of Chemistry (RSC)

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