Cu(i) based catalysts derived from bidentate ligands and studies on the effect of substituents for N-arylation of benzimidazoles and indoles-Reference-Cited by-同舟云学术

Cu(i) based catalysts derived from bidentate ligands and studies on the effect of substituents for N-arylation of benzimidazoles and indoles

Published:2020 Issue:45 Volume:44 Page:19591-19597
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Kumari Sheela¹²³⁴^ORCID,Ratnam Anand¹⁵⁶⁴^ORCID,Mawai Kiran¹²³⁴,Chaudhary Virendra Kumar¹²³⁴^ORCID,Mohanty Aurobinda¹²³⁴^ORCID,Ghosh Kaushik¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Roorkee

3. Roorkee 247667

4. India

5. DDU Gorakhpur University

6. Gorakhpur

Abstract

Four Cu(i) complexes [Cu(L^1–4)(Cl)(PPh₃)] (C1–C4) were synthesized, characterized and crystal structure of C1 was determined. Complexes were utilized as catalysts for N-arylation reaction. Probable mechanism for N-arylation reaction was proposed.

Funder

Council of Scientific and Industrial Research, India

University Grants Commission

Ministry of Human Resource Development

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ02568B

Reference53 articles.

1. Palladium-catalyzed aerobic oxidative C–H amination: synthesis of 2-unsubstituted and 2-substituted N-aryl benzimidazoles