Cu(i) complexes obtained via spontaneous reduction of Cu(ii) complexes supported by designed bidentate ligands: bioinspired Cu(i) based catalysts for aromatic hydroxylation-Reference-Cited by-同舟云学术

Cu(i) complexes obtained via spontaneous reduction of Cu(ii) complexes supported by designed bidentate ligands: bioinspired Cu(i) based catalysts for aromatic hydroxylation

Published:2020 Issue:39 Volume:49 Page:13829-13839
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kumari Sheela¹²³⁴^ORCID,Muthuramalingam Sethuraman⁵⁶⁷⁸⁴^ORCID,Dhara Ashish Kumar¹²³⁴,Singh U. P.¹²³⁴^ORCID,Mayilmurugan Ramasamy⁵⁶⁷⁸⁴^ORCID,Ghosh Kaushik¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Roorkee

3. Roorkee-247667

4. India

5. Bioinorganic Chemistry Laboratory/Physical Chemistry

6. School of Chemistry

7. Madurai Kamaraj University

8. Madurai-625021

Abstract

Cu(i) complexes were synthesized via spontaneous reduction and X-ray crystal structure of complex 1 was determined. Direct hydroxylation of benzene to phenol afforded selectivity up to 98%. KIE values of 1.69–1.71 supported radical based mechanism.

Funder

University Grants Commission

Ministry of Human Resource Development

Science and Engineering Research Board

Council of Scientific and Industrial Research, India

Council for Scientific and Industrial Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02413A