Role of 4,4′-bipyridine versus longer spacers 4,4′-azobipyridine, 1,2-bis(4-pyridyl)ethylene, and 1,2-bis(pyridin-3-ylmethylene)hydrazine in the formation of thermally labile metallophosphate coordination polymers

Author:

Rajakannu Palanisamy1234,Howlader Rana1234,Kalita Alok Ch.1234ORCID,Butcher Raymond J.1567,Murugavel Ramaswamy1234

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Bombay

3. Mumbai 400 076

4. India

5. Howard University

6. Washington

7. USA

Abstract

Uncoordinated N-donors spacers in the title compounds facilitate interesting orthogonal H-bonding, leading to the formation of 3-D polymeric networks.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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