The reaction of organic peroxy radicals with unsaturated compounds controlled by a non-epoxide pathway under atmospheric conditions-Reference-Cited by-同舟云学术

The reaction of organic peroxy radicals with unsaturated compounds controlled by a non-epoxide pathway under atmospheric conditions

Published:2023 Issue:11 Volume:25 Page:7772-7782
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Nozière Barbara¹^ORCID,Durif Olivier¹^ORCID,Dubus Eloé¹,Kylington Stephanie¹,Emmer Åsa¹,Fache Fabienne²^ORCID,Piel Felix³,Wisthaler Armin³

Affiliation:

1. KTH, Royal Institute of Technology, Department of Chemistry, 114 28 Stockholm, Sweden

2. Université Lyon 1 and CNRS, UMR 5246, ICBMS, 69626 Villeurbanne, France

3. University of Oslo, Department of Chemistry, 0315 Oslo, Norway

Abstract

Reactions of organic peroxy radicals (RO2) with alkenes at room temperature were found to proceed by the formation of large peroxy radicals (ROO-R’O2) instead of epoxides, which was reported until now for these reactions in combustion systems.

Funder

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D2CP05166D

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