Mechanistic study of the reaction of CH2F2 with Cl atoms in the absence and presence of CH4 or C2H6: decomposition of CHF2OH and fate of the CHF2O radical-Reference-Cited by-同舟云学术

Mechanistic study of the reaction of CH2F2 with Cl atoms in the absence and presence of CH4 or C2H6: decomposition of CHF2OH and fate of the CHF2O radical

Published:2019 Issue:18 Volume:21 Page:9376-9383
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Østerstrøm Freja F.¹²³⁴⁵^ORCID,Andersen Christina¹²³,da Silva Gabriel⁶⁷⁸^ORCID

Affiliation:

1. Copenhagen Center for Atmospheric Research, Department of Chemistry, University of Copenhagen

2. 2100 Copenhagen

3. Denmark

4. School of Chemistry, University of Leeds

5. Leeds

6. Department of Chemical Engineering, University of Melbourne

7. Victoria 3010

8. Australia

Abstract

First experimental and theoretical study determining the atmospheric fates of CHF₂OH and CHF₂O; products from degradation of a chlorofluorocarbon replacement.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C8CP06425C

Reference42 articles.

1. Stratospheric sink for chlorofluoromethanes: chlorine atom-catalysed destruction of ozone

2. Large losses of total ozone in Antarctica reveal seasonal ClOx/NOx interaction

3. IPCC , Climate Change 2013: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change , Cambridge University Press , Cambridge, United Kingdom and New York, NY, USA , 2013

4. WMO , Scientific Assessment of Ozone Depletion: 2014, Global Ozone Research and Monitoring , 2014

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