Thermal decomposition mechanism and kinetics of perfluorooctanoic acid (PFOA) and other perfluorinated carboxylic acids: a theoretical study-Reference-Cited by-同舟云学术

Thermal decomposition mechanism and kinetics of perfluorooctanoic acid (PFOA) and other perfluorinated carboxylic acids: a theoretical study

Published:2022 Issue:12 Volume:24 Page:2475-2487
ISSN:2050-7887
Container-title:Environmental Science: Processes & Impacts
language:en
Short-container-title:Environ. Sci.: Processes Impacts

Author:

Khan M. Yasir¹^ORCID,Song Jiaou¹,Narimani Milad¹^ORCID,da Silva Gabriel¹^ORCID

Affiliation:

1. Department of Chemical Engineering, University of Melbourne, Victoria 3010, Australia

Abstract

PFOA decomposition initiates via HF elimination and formation of perfluorinated α-lactone. Perfluorinated α-lactone readily releases CO, forming perfluorinated acyl fluoride. Wet-decomposition completely mineralizes PFOA to HF, COx, COF2, and CF2.

Funder

University of Melbourne

Publisher

Royal Society of Chemistry (RSC)

Subject

Management, Monitoring, Policy and Law,Public Health, Environmental and Occupational Health,Environmental Chemistry,General Medicine

Link

http://pubs.rsc.org/en/content/articlepdf/2022/EM/D2EM00259K

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