Effective tuning of magnetic anisotropy in distorted pentagonal bipyramidal Ni(<scp>ii</scp>) complexes <i>via</i> substitution of axial coligands-Reference-Cited by-同舟云学术

Effective tuning of magnetic anisotropy in distorted pentagonal bipyramidal Ni(ii) complexes via substitution of axial coligands

Published:2022 Issue:47 Volume:51 Page:18033-18044
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Drahoš Bohuslav¹^ORCID,Herchel Radovan¹^ORCID

Affiliation:

1. Department of Inorganic Chemistry, Faculty of Science, Palacký University, 17. listopadu 12, CZ-771 46 Olomouc, Czech Republic

Abstract

Unexpected variation of the magnetic anisotropy in pentagonal bipyramidal Ni(ii) complexes induced by different axial co-ligands due to a strong distortion of the equatorial pentagonal ligand field.

Funder

Univerzita Palackého v Olomouci

Ministerstvo Školství, Mládeže a Tělovýchovy

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02867K

Reference77 articles.

1. Magnetic anisotropy of transition metal and lanthanide ions in pentagonal bipyramidal geometry

2. Single-ion magnet behaviour of heptacoordinated Fe(ii) complexes: on the importance of supramolecular organization

3. Pentagonal Bipyramid FeII Complexes: Robust Ising-Spin Units towards Heteropolynuclear Nanomagnets

4. Late First-Row Transition-Metal Complexes Containing a 2-Pyridylmethyl Pendant-Armed 15-Membered Macrocyclic Ligand. Field-Induced Slow Magnetic Relaxation in a Seven-Coordinate Cobalt(II) Compound

5. Spin canting, metamagnetism, and single-chain magnetic behaviour in a cyano-bridged homospin iron(ii) compound

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