Single-ion magnet behaviour of heptacoordinated Fe(ii) complexes: on the importance of supramolecular organization

Author:

Bar Arun Kumar12345,Pichon Céline12345,Gogoi Nayanmoni12345,Duhayon Carine12345,Ramasesha S.678,Sutter Jean-Pascal12345

Affiliation:

1. CNRS

2. LCC

3. F-31077 Toulouse

4. France

5. Université de Toulouse

6. Indian Institute of Science

7. Bangalore 560012

8. India

Abstract

Supramolecular organization is shown to contribute to the magnetization dynamics of mononuclear SMMs, leading to the first example of single-ion magnet behaviour of Fe(ii) in a D5h surrounding.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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