Chiral discrimination of α-hydroxy acids and N-Ts-α-amino acids induced by tetraaza macrocyclic chiral solvating agents by using 1H NMR spectroscopy-Reference-Cited by-同舟云学术

Chiral discrimination of α-hydroxy acids and N-Ts-α-amino acids induced by tetraaza macrocyclic chiral solvating agents by using 1H NMR spectroscopy

Published:2017 Issue:7 Volume:15 Page:1642-1650
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Lv Caixia¹²³⁴,Feng Lei¹²³⁴,Zhao Hongmei⁵⁶⁷⁸⁴,Wang Guo⁹¹⁰¹¹⁴,Stavropoulos Pericles⁹¹²¹³¹⁴,Ai Lin¹²³⁴^ORCID

Affiliation:

1. College of Chemistry

2. Beijing Normal University

3. Beijing 100875

4. P. R. China

5. Beijing National Laboratory for Molecular Sciences

6. Institute of Chemistry

7. Chinese Academy of Sciences

8. Beijing 100190

9. Department of Chemistry

10. Capital Normal University

11. Beijing 10048

12. Missouri University of Science and Technology

13. Rolla

14. USA

Abstract

Several α-hydroxy acids and N-Ts-α-amino acids were effectively discriminated in the presence of tetraaza macrocyclic chiral solvating agents (TAMCSAs) 1a–1d by ¹H NMR spectroscopy.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/OB/C6OB02578A

Reference40 articles.

1. Enantiodiscrimination of carboxylic acids using the diphenylprolinol NMR chiral solvating agents

2. Application of L-proline derivatives as chiral shift reagents for enantiomeric recognition of carboxylic acids

3. Molecular recognition and activation by polyaza macrocyclic compounds based on host–guest interactions

4. Chiral Sensor for Enantiodiscrimination of Varied Acids

5. The Assignment of Absolute Configuration by NMR

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