Crystal structure and in situ decomposition of Eu(BH4)2 and Sm(BH4)2-Reference-Cited by-同舟云学术

Crystal structure and in situ decomposition of Eu(BH4)2 and Sm(BH4)2

Published:2015 Issue:2 Volume:3 Page:691-698
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Humphries Terry D.¹²³⁴⁵,Ley Morten B.⁶⁷⁸⁹¹⁰,Frommen Christoph¹²³⁴,Munroe Keelie T.⁶⁷⁸⁹¹⁰,Jensen Torben R.⁶⁷⁸⁹¹⁰,Hauback Bjørn C.¹²³⁴

Affiliation:

1. Physics Department

2. Institute for Energy Technology

3. Kjeller

4. Norway

5. WPI-Advanced Institute for Materials Research

6. Centre for Materials Crystallography (CMC)

7. Interdisciplinary Nanoscience Center (iNANO) and Department of Chemistry

8. University of Aarhus

9. DK-8000 Århus C

10. Denmark

Abstract

Synthesis of halide free RE(BH₄)₂ (RE = Eu, Sm) complexes are detailed. Their crystal structures have been determined and thermal decomposition pathways studied by in situ SR-PXD and thermal analysis techniques.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/TA/C4TA04080E

Reference37 articles.

1. Complex hydrides for hydrogen storage – new perspectives

2. Synthesis, Crystal Structure, and Thermal Properties of the First Mixed-Metal and Anion-Substituted Rare Earth Borohydride LiCe(BH4)3Cl

3. Crystal structures and properties of solvent-free LiYb(BH4)4−xClx, Yb(BH4)3 and Yb(BH4)2−xClx

4. New Li Ion Conductors and Solid State Hydrogen Storage Materials: LiM(BH4)3Cl, M = La, Gd

5. LiCe(BH4)3Cl, a New Lithium-Ion Conductor and Hydrogen Storage Material with Isolated Tetranuclear Anionic Clusters

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