Reconciling experimental and theoretical vibrational deactivation in low-energy O + N2 collisions

Author:

Hong Qizhen12345ORCID,Bartolomei Massimiliano678ORCID,Esposito Fabrizio9101112ORCID,Coletti Cecilia13141512ORCID,Sun Quanhua12345ORCID,Pirani Fernando1617181912ORCID

Affiliation:

1. State Key Laboratory of High Temperature Gas Dynamics

2. Institute of Mechanics

3. Chinese Academy of Sciences

4. 100190 Beijing

5. China

6. Instituto de Física Fundamental-CSIC

7. Madrid

8. Spain

9. Consiglio Nazionale delle Ricerche

10. Istituto per la Scienza e Tecnologia dei Plasmi

11. Sede Secondaria di Bari

12. Italy

13. Dipartimento di Farmacia

14. Università G. d’Annunzio Chieti-Pescara

15. 66100 Chieti

16. Dipartimento di Chimica

17. Biologia e Biotecnologie

18. Università di Perugia

19. 06123 Perugia

Abstract

The large vibrational deactivation, experimentally found in low-energy O + N2 collisions, is quantitatively reproduced only using a vibronic mechanism.

Funder

Chinese Academy of Sciences

National Natural Science Foundation of China

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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