Synthesis and characterization of novel barbwire-like graft polymers poly(ethylene oxide)-g-poly(ε-caprolactone)4 by the ‘grafting from’ strategy

Author:

Liang Xinyi12345,Liu Yujie12345,Huang Jian12345,Wei Liuhe678910,Wang Guowei12345

Affiliation:

1. State Key Laboratory of Molecular Engineering of Polymers

2. Department of Macromolecular Science

3. Fudan University

4. Shanghai 200433

5. China

6. Zhengzhou Key Laboratory of Elastic Sealing Materials

7. College of Chemistry and Molecular Engineering

8. Zhengzhou University

9. Zhengzhou 450001

10. PR China

Abstract

Novel barbwire-like graft polymers PEO-g-PCL4 were synthesized by combination of ring opening polymerization (ROP) and Glaser coupling with thiol–yne addition reaction via the “grafting from” strategy.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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