Formation of ortho-cyano-aminothiophenolate ligands with versatile binding modes via facile carbon–sulfur bond cleavage of 2-aminobenzothiazoles at mercury(ii) centres-Reference-Cited by-同舟云学术

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Formation of ortho-cyano-aminothiophenolate ligands with versatile binding modes via facile carbon–sulfur bond cleavage of 2-aminobenzothiazoles at mercury(ii) centres

Published:2015 Issue:32 Volume:44 Page:14217-14219
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Al-Jibori Subhi A.¹²³⁴⁵,Irzoqi Ahmed A.¹⁶³⁴⁵,Al-Saraj Emad G. H.¹²³⁴⁵,Al-Janabi Ahmed S. M.¹⁷³⁴⁵,Basak-Modi Sucharita¹⁸⁹¹⁰,Ghosh Shishir¹⁸⁹¹⁰,Merzweiler Kurt¹¹¹²¹³¹⁴,Wagner Christoph¹¹¹²¹³¹⁴,Schmidt Harry¹¹¹²¹³¹⁴,Hogarth Graeme¹¹⁵⁹¹⁰

Affiliation:

1. Department of Chemistry

2. College of Science

3. University of Tikrit

4. Tikrit

5. Iraq

6. College of Education

7. College of Veterinary Medicine

8. University College London

9. London

10. UK

11. Institute für Chemie

12. Martin-Luther-Universität

13. D-06120 Halle

14. Germany

15. King's College London

Abstract

Mercuric acetate and 2-aminobenzothiazoles react to give novel ortho-cyano-aminothiophenolate complexes via sulfur–carbon bond cleavage and H₂ loss.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02080H

Reference31 articles.

1. Molecular and electronic structures of new iron complexes containing N,S-coordinated o-iminothionebenzosemiquinonate(1-) π radical ligands: An experimental and density functional theoretical study

2. Molecular and Electronic Structures of Iron Complexes Containing N,S-Coordinated, Open-Shell o-Iminothionebenzosemiquinonate(1−) π Radicals

3. Molecular and Electronic Structures of Iron(II)/(III) Complexes Containing N,S-Coordinated, Closed-Shell o-Aminothiophenolato(1−) and o-Iminothiophenolato(2−) Ligands

4. o-Dithiolene and o-aminothiolate chemistry of iron: Synthesis, structure and reactivity

5. Ruthenium Complexes of Quinone Related Ligands: A Study of the Electrochemical Properties of 2-Aminothiophenolatobis(2,2‘-Bipyridine)Ruthenium(II)

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Synthesis, spectroscopic and hydrogen storage studies of mono or bimercury(II) mixed ligand complexes of amines with 2-cyanoamino thiophenolate ligand;Journal of Molecular Structure;2023-11

2. Reactivity of Hg(II) ortho-cyano-aminothiophenolate coordination polymers [Hg{SC₆H₃XN(C≡N)}]_n with cyclic aromatic amines, Ph₃P = E (E = O, S) and [HgCl₂(κ²-phen)];Journal of Coordination Chemistry;2022-05-19

3. Palladium(ii) ortho-cyano-aminothiophenolate (ocap) complexes;Dalton Transactions;2022

4. Synthesis, structure and reactivity with phosphines of Hg(ii) ortho-cyano-aminothiophenolate complexes formed via C–S bond cleavage and dehydrogenation of 2-aminobenzothiazoles;Dalton Transactions;2022

5. Mercury(II) mixed ligand complexes of phosphines or amines with 2-cyanoamino thiophenolate ligands formed via monodeprotonation and carbon–sulfur bond cleavage of 2-aminobenzothiazole. X-ray crystal structures of [Hg(SC6H4NCN)(PPh3)]2 and [Hg(SC6H4NCN)(Ph2PCH2PPh2)]2;Polyhedron;2021-09

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