Synthesis, structure and reactivity with phosphines of Hg(<scp>ii</scp>) <i>ortho</i>-cyano-aminothiophenolate complexes formed <i>via</i> C–S bond cleavage and dehydrogenation of 2-aminobenzothiazoles-Reference-Cited by-同舟云学术

Synthesis, structure and reactivity with phosphines of Hg(ii) ortho-cyano-aminothiophenolate complexes formed via C–S bond cleavage and dehydrogenation of 2-aminobenzothiazoles

Published:2022 Issue:20 Volume:51 Page:7889-7898
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Al-Jibori Subhi A.¹,Irzoqi Ahmed A.²,Al-Janabi Ahmed S. M.³^ORCID,Al-Nassiry Amenah I. A.²,Basak-Modi Sucharita⁴,Ghosh Shishir⁴,Wagner Christoph⁵,Hogarth Graeme⁶^ORCID

Affiliation:

1. Department of Chemistry, College of Science, University of Tikrit, Tikrit, Iraq

2. Department of Chemistry, College of Education, University of Tikrit, Tikrit, Iraq

3. Department of Biochemistry, College of Veterinary Medicine, University of Tikrit, Tikrit, Iraq

4. Department of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ, UK

5. Institute für Chemie, Martin-Luther-Universität, Halle-Wittenberg, Kurt-Mothes-Str.2, D-06120 Halle, Germany

6. Department of Chemistry, King's College London, Britannia House, 7 Trinity Street, London, SE1 1DB, UK

Abstract

Hg(ii) ortho-cyano-aminothiophenolate (ocap) complexes [Hg{SC6H3XN(CN)}]n (X = H, Me, Cl, Br, NO2) have been prepared from dehydrogenation and C–S bond cleavage of 2-aminobenzothiazoles.

Funder

Tikrit University

King’s College London

Erasmus+

Commonwealth Scholarship Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00391K

Reference52 articles.