Substitution of lead with tin suppresses ionic transport in halide perovskite optoelectronics

Author:

Dey Krishanu1ORCID,Ghosh Dibyajyoti2ORCID,Pilot Matthew3,Pering Samuel R.4ORCID,Roose Bart5ORCID,Deswal Priyanka6ORCID,Senanayak Satyaprasad P.7,Cameron Petra J.3ORCID,Islam M. Saiful8ORCID,Stranks Samuel D.15ORCID

Affiliation:

1. Cavendish Laboratory, University of Cambridge, Cambridge, UK

2. Department of Materials Science and Engineering and Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, India

3. Department of Chemistry, University of Bath, Bath, UK

4. Department of Materials, Loughborough University, Loughborough, UK

5. Department of Chemical Engineering and Biotechnology, University of Cambridge, Cambridge, UK

6. Department of Physics, Indian Institute of Technology Delhi, Hauz Khas, India

7. Nanoelectronics and Device Physics Lab,School of Physical Sciences, National Institute of Science Education and Research, HBNI, Jatni, India

8. Department of Materials, University of Oxford, Oxford, UK

Abstract

Mobile ions cause deterioration in both device performance and stability of lead halide perovskite devices. This study provides direct evidence for substantial suppression of ionic migration effects in tin-containing perovskite compositions.

Funder

Engineering and Physical Sciences Research Council

H2020 European Research Council

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

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