Octahedral Werner complexes with substituted ethylenediamine ligands: a stereochemical primer for a historic series of compounds now emerging as a modern family of catalysts
Author:
Affiliation:
1. Department of Chemistry
2. Texas A&M University
3. College Station
4. USA
Abstract
The title compounds exhibit metal centered chirality (Λ/Δ), chelate conformers (λ/δ), configurational diastereomers (R/S) due to carbon stereocenters, geometric isomers (fac/mer), and C–C bond/C3axis alignment modes (lel/ob).
Funder
Welch Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CS/C6CS00604C
Reference67 articles.
1. A. von Zelewsky , Stereochemistry of Coordination Compounds, John Wiley & Sons, Chichester, 1996
2. H. Amouri and M.Gruselle, Chirality in Transition Metal Chemistry, John Wiley & Sons, Chichester, 2008
3. C. J. Hawkins , Absolute Configuration of Metal Complexes, Wiley-Interscience, New York, 1971
4. Alfred Werner's research on optically active coordination compounds
5. Zur Kenntnis des asymmetrischen Kobaltatoms. I
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