A non-innocent pincer H3LONS ligand and its corresponding octahedral low-spin Fe(iii) complex formation via ligand-centric homolytic S

A non-innocent pincer H3LONS ligand and its corresponding octahedral low-spin Fe(iii) complex formation via ligand-centric homolytic S–S bond scission

Published:2018 Issue:38 Volume:47 Page:13337-13341
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sarkar Prasenjit¹²³⁴,Mukherjee Chandan¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Guwahati

3. Guwahati

4. India

Abstract

Ligand-based S–S bond cleavage led to an unprecedented, homoleptic, six-coordinate, low-spin Fe(iii) complex comprising two 2-iminobenzosemiquinone and one thiyl π-radical.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT02763C

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